Showing posts with label carbon. Show all posts
Showing posts with label carbon. Show all posts

2011-06-24

Comparing volcanic CO2 emissions to human-made emissions

There's a terrific article by T. Gerlach in last week's issue of AGU's EOS newspaper [PDF]. Gerlach is apparently a volcanologist, not a climate scientist. The article compares estimates of CO2 emission by volcanic sources to human-made emissions. There is a common misconception (I'm not sure how common) about the relative contributions of volcanos and humans to the emission of CO2.

So, which do you think is the larger source of CO2, global volcanos or human-made sources (includes land-use change, cement production, transport, energy, etc)?


The answer is that humans produce (as of 2010) about 135 times more CO2 than all the volcanoes in the world. The numbers are something like humans emitting about 35 billion tons versus volcanoes emitting 260 million tons. There doesn't appear to be any tricky business going on, and all kinds of volcanoes (including underwater volcanoes) are included. In fact, Gerlach goes on to make lots of interesting comparisons: one good one is that human activities produce the same amount of CO2 emissions as the global volcanic annual source every 12.5 hours.

Gerlach also accounts for the explosive volcanic eruptions like Mount St. Helens and Pinatubo, which are called paroxysms. These can suddenly emit a lot of CO2, but they are rare. While these paroxysms are happening, their emission rate might be as large as all of humanity's. The catch is that they only last a few hours, and wind up contributing very little to the global CO2 emissions.

Really nailing the coffin shut, Gerlach also considers what it would mean for volcanism if the emission rate did match the human-made CO2 emissions of  about 135 Gigatons per year. It sounds like it would mean that we would need one (or more) supereruptions per year. Supereruptions are huge volcanic eruptions, like when Yellowstone blew up 2 million years ago, and they are rare even for geologists, happening only every 100,000-200,000 years or so.

The only weakness of the article is that Gerlach forgets to address the obvious climate change denial argument that humans are not emitting as much CO2 as claimed. There are hints of how to deal with this, however, as Gerlach mentions that the total volcanic emission is equal to that of about two dozen large coal-fired power plants. The volcanic number is so small that we can easily eliminate huge amounts of human-made emissions and still have more human-made emissions than volcanic emissions by more than an order of magnitude. So I think this presentation is a great place to point to really come to terms with this comparison, and the vast difference in the volcanic versus human-made emissions means that there can be no dispute.

Also see another Gerlach article at EARTH Magazine [LINK].

2010-09-13

What if we just stopped doing things for the next couple decades?

That's essentially the though experiment discussed by Davis et al. in last week's Science [LINK]. They tried to estimate what climate change would occur if CO2-emitting devices that currently exist were used until their expected lifetime, at which point they are taken offline and non-emitting devices are installed. Basically, they say, okay, we've got a lot of coal-fired power plants (and gas or oil plants and also cars and trucks), so what if we just use them until they're not good (say ~35 years for power plants)? In the interim, no additional CO2-emitting devices are introduced. The conclusion is that, based on a vast set of rough approximations and an intermediate complexity climate model, the atmospheric CO2 could be kept below 430 ppm, keeping global warming at a "comfortable" 1.3 degrees or so.

From my reading of the paper, the important insight is that the most dangerous CO2 emissions -- those that will take us past 450ppm and then past 550ppm -- have not yet been built. This is a scary realization because if their estimates are close, then we know we aren't committed to "dangerous anthropogenic warming" yet, but we're about to be. We see what's coming, but won't do anything about it. We're like the proverbial lemmings heading over the cliff.

Now, realistically we might be in worse shape than the scenarios addressed in the paper, and the authors acknowledge that. In particular, since there are such strong economic/societal incentives to use the cheap (but dirty) fuel sources, it is impossible to achieve a scenario that is even remotely like the one simulated by Davis et al. At the end, they also touch on the China and India issues. These countries are in the midst of rapid industrialization, and they aren't going to turn back. And they are going to account for a large amount of the accumulated emissions over the next 50 years or more. The developing world, under the Davis et al. scenario, would be left behind, too, unless they employ an incredible leap-frog to using clean energy sources. In the end, this study the idealistic scenario, one small step past the most idealized scenario of 'what if we stop emitting CO2 completely today?' The lessons we learn directly are mostly about what we are committed to already. That makes these kinds of studies very policy relevant, but of course few policy makers seem to care. Indirectly, science also progresses, as these are the kinds of studies that help us understand the interactions between the societal decisions and the climate system, and can lead to more fundamental understanding of timescales in the perturbed climate system.

--------
Reference:
Steven J. Davis, Ken Caldeira, H. Damon Matthews
Emissions and Climate Change from Existing Energy Infrastructure
Science, Vol. 329 no. 5997 pp. 1330-1333
10 September 2010
DOI: 10.1126/science.1188566

2010-06-16

Why make a point when you can just sound like you are?

Just read an article on Reuters with the headline: Whale poo helps offset carbon footprint. Sometimes articles get stupid headlines because the person writing the article isn't in charge of making the headline, but this article actually says this in the text. It's real short, go read it. I doubt you'll be as angered by it as I am, but maybe you'll see how incredibly stupid it is.

The story reports on science, which says that sperm whales in the Southern Ocean defecate in the upper ocean where phytoplankton use the iron from the feces to grow. This in turn, allows the phytoplankton to "absorb" more carbon. The idea is just like iron fertilization.

The point that they article makes is that the cycle actually reduces atmospheric CO2 because the amount of carbon used by the phytoplankton is twice as much as is breathed out by the whales. Thus, Michael Perry (the reporter) concludes, the whales offset their carbon and reduce their carbon footprint.

First off, whales don't have feet, so they have no footprint.

Second, though, whales also don't use fossil fuels, so whales have no carbon footprint.

The science sounds interesting enough, and it seems like they are showing that this aspect of the carbon cycle is a net sink of atmospheric carbon. One caveat that isn't dealt with is that the phytoplankton don't necessarily use the carbon immediately die and sink, there is also a lot of recycling in the upper ocean. So this "carbon sequestration" (which just means that the phytoplankton die and sink to the deep ocean) might not be as strong as this news article would lead us to believe.

A larger point is that in the absence of humans, this would just be one of many small carbon sinks that would balance a lot of carbon sources, closing the carbon cycle. Unperturbed ecosystems, much less individual species, are (over long time scales) in steady-state. Imagine that humans disappear, so all the anthropogenic CO2 stays around, but no more is added. These whales(+phytoplankton) might continue to act as a net carbon sink, but over the long run, they aren't going to suck all the carbon out of the atmosphere. Okay, I'll stop belaboring this point.

What makes this an even better example of lazy science reporting is that the really interesting point about the whales'(+phytoplankton's) role in the carbon cycle is buried in the last sentence:
Lavery said that without whaling there may have been 120,000 sperm whales in the Southern Ocean and, according to her calculations, some 2 million tonnes of carbon may have been removed from the atmosphere each year through this process.
So what this says is that if the whale population was what it should be, the carbon source would be ten times larger (there are currently ~12,000 sperm whales in the Southern Ocean). So the interesting twist, in my opinion, isn't that the whales are "carbon negative," but really that whaling represents an increase in atmospheric CO2 by reducing a natural sink. This is just like (though much smaller than) land-use change, which removes carbon-absorbing ecosystems with cropland, removing a terrestrial sink. Does this raise the question of whether over-fishing represents such a decrease in a natural sink? So instead of going off half-cocked to do geoengineering through iron fertilization [e.g.], we should make a legitimate attempt to allow the natural ocean ecosystems to recover from the past couple of centuries of abuse.

UPDATE:
An AP story also has most of this, but better covers the whaling angle: [LINK]

2009-08-01

The Indian problem

I was just reading a Grist article about India wanting a global agreement on combatting climate change, while at the same time opposing binding emissions limits [LINK]. This has been, and I think will remain, a key issue for international agreements and negotiations concerning climate change. India and China have a couple of billion people, many of whom live in abject poverty. Both countries are making long strides in their development, becoming global powerhouses in terms of manufacturing and providing low-cost services to the "developed world." In this dash to bring the standard of living in China and India into alignment with the developed countries, the fossil-fuel use in these nations has increased tremendously. Of course, at the same time most Indians still burn biomass for cooking and heating [LINK, see also video].

So on the face of it, this seems to be a dilemma. India and China want to lift their populations out of poverty, expand their economies, and become global leaders. Doing this requires dramatic increases in infrastructure, and includes expanding electricity and water resources. The apparent consequence is increased carbon emissions. So, from the perspective of these developing nations, to improve the standard of living for their populations requires intensive use of fossil fuels and increased emissions, and from their perspective it's not fair that just when they are making progress the "West" tells them that they can't use the cheap (and dirty) energy that will accelerate their endeavors. From the outsider's point of view, though, ramping up the carbon emissions is bad for the whole world.

The only solution that I see to this dilemma is actually exactly what India says it doesn't want: binding emissions restrictions. Such restrictions could be quite complicated in their details, but the point is to prevent the infrastructure in developing nations from building in a dependence on fossil fuels. The world's developed nations are now addicted to fossil fuel, and it is obvious that this has become an impediment to combatting climate change. Introducing the same addiction for another 30% of the world's population doesn't seem useful. Instead, by introducing binding emissions cuts for everyone (and that is key!), the developing nations will be able to practically leap-frog the fossil-fuel phase that the west has been stuck in for a century. It'll be cost efficient, too, since all the western nations are transitioning away from fossil fuels, driving the prices of renewable energy technology down. So while all the developing nations are spending gads of money to deconstruct their antiquated systems while building up entirely new infrastructure for a low-carbon future, India and China should be able to simply begin with renewable systems (for much of their countries at least). This strategy would actually accelerate China and India's progress in catching up with developed countries because they'd avoid what will undoubtedly be a painful transition away from fossil fuels, while pioneering the large-scale use of renewable energy technologies.

Of course, this has all been about energy and money. There are a host of issues related to the impacts of climate change that will disproportionately hurt developing nations, so avoiding those impacts should be a very high priority for those countries. Maybe we should review some of those issues in a future post.


2009-07-31

Short german video

Below find a nice short film about fossil-fuel based life. It's in German (w/English subtitles), and focuses on a German audience. Is there an equivalent film for the US?

2009-07-01

Waxman-Markey, or some derivative thereof

The NYTimes has an article about the wheeling and dealing going on to get the Waxman-Markey climate/energy legislation through the House [LINK]. It sounds so dirty and counterproductive, but I guess that is how things work in Congress, and without substantial changes to the system, it is the way it has to be. In the end, the Senate is likely to pass the bill, and Obama will sign it into law, and then the USA will finally enter the 21st Century on energy/climate legislation. The questions will remain though: Is it enough? Will it be regulated strongly enough? Do the new rules constrain more powerful action in the future? I don't know the answers to these questions, but with the atmosphere holding 386+ ppm of CO2 [LINK], something has to be done now, so I have to at least support the spirit of the bill. With the recent Copenhagen Synthesis Report urging action, the USA needs to position itself as a leader (if a tardy one) in the mitigation of climate change.

2009-06-01

EPA says carbon emissions to rise (is that a surprise?)

Last week the EPA issued a report that, according the news accounts, says carbon emissions will rise in the next 20 years by about 40%. Here's a link to a very poorly written article: LINK.

So, just thinking out loud here, but the current rise in CO2 concentration is around 2ppm/year (confirmation). If that were constant, then 20 years would be an increase of 40 ppm, taking us to around 420ppm CO2.

Just eye-balling the emissions to concentration curves (curves) suggests a linear fit of about 10ppm increase for every 1Gt increase in emissions. That news article says
As a result, the analysis predicted a steady increase in emissions of carbon dioxide, the greenhouse gas that scientists say threatens a serious warming of the Earth later this century. Between now and 2030, Wednesday's report said, global carbon dioxide pollution is expected to increase by 39%. That translates to 33 billion metric tons in 2015 and 40 billion metric tons by 2030, compared to 29 billion metric tons in 2006, the report said.
So a 40% increase according to that news article is going from 29 to 40, that's 40 divided by 29 (= 1.38, so about 38% increase). The emissions increase by just 11 Gt/year. Using our poor estimate of 10ppm/1Gt, that means 10*11= 110ppm!!

UPDATE: This is mistaken. After consultation with somebody who knows about carbon, I think the way I should have done that is to say that there's a 10ppm increase for a 1Gt/year increase in emission rate. The change from 29 to 40 Gt appears to be the cumulative emissions. This, however, suggests a much lower increase in atmospheric CO2. It isn't totally clear how to make the estimate without making a budget for carbon. I'll try to make that estimate and re-update later.

2009-05-23

Saturday means a video

Okay... not every saturday means a video, but this one does.

I just wanted to share this week's installment of Climate Denial Crock of the Week with Peter Sinclair, which I have to admit that I've really taken to in the past couple weeks. It is a series of well-produced (by internet standards) short videos that dissect global warming deniers arguments.

This video is actually directly related to a pair of recent posts, in which I showed you Rep. Boehner being a jack-hole and also explained that breathing does not produce a net source of carbon dioxide. It's like blogosphere synergy!


2009-05-13

Marathon runners not a source of CO2 to atmosphere -- shocker!

I'm so glad that RSS exists, so that I don't miss stories like "Barton worries that EPA will regulate runners" from Kate Sheppard at Grist. Did you read it yet? Just in case you didn't, let me recap for you. Representative (from Texas) Joe Barton (Republican) is the ranking Republican on the Energy and Commerce Committee, which means he's the most senior Republican on the committee. This committee's role is, from Wikipedia:

The House Committee on Energy and Commerce has developed what is arguably the broadest (non-tax-oriented) jurisdiction of any Congressional committee. Today, it maintains principal responsibility for legislative oversight relating to telecommunications, consumer protection, food and drug safety, public health, air quality and environmental health, the supply and delivery of energy, and interstate and foreign commerce in general. This jurisdiction extends over five Cabinet-level departments and seven independent agencies--from the Energy Department, Health and Human Services, the Transportation Department to the Federal Trade Commission, Food and Drug Administration, and Federal Communications Commission — and sundry quasi-governmental organizations.

Which is to say, this is a pretty powerful committee. They get to advance (or squelch) a lot of potentially important legislation. And Barton, as ranking member, is a powerful guy within this powerful committee. So it matter that he thinks crazy things, like that marathon runners could be considered a source of pollution. Yeah, didn't you read that article? It goes back to the EPA's decision that carbon dioxide can be considered a pollutant, and as such can be regulated. Barton thinks that people are point sources of carbon dioxide, and I guess because marathons are a large group of heavily exhaling people, Joe thinks that means a large source of carbon dioxide to the atmosphere.

The point Barton is trying, and failing, to make is that carbon dioxide is difficult to regulate because it is a naturally occurring substance that is a basic part of all life on Earth. The reason he is trying to make this point is because he doesn't want to believe that the EPA has the right to regulate carbon dioxide. There are two reasons he doesn't want to accept that. First, because he's a Republican, and that party has decided to oppose regulation of nearly any kind. (Examples, regulating financial institutions like AIG or energy brokers like Enron.) Second, as part of Barton's ideology, he can't accept that humans affect the Earth adversely, so he emotionally reacts to climate change by denying it.

The point I want to make is that Barton is wrong about marathon runners. They aren't a source of carbon dioxide to the atmosphere, even though they do exhale carbon dioxide. The reason is that humans are part of the terrestrial biosphere, which is part of the global carbon cycle, which is basically in balance except for the perturbation from burning fossil fuels. To see this, think about that air you just exhaled, which is relatively enriched in carbon dioxide. Note, you don't breathe in pure oxygen, and you don't exhale pure carbon dioxide. How did that CO2 get into your breath? It is a byproduct of your physiology, mostly it come from breaking down sugars, which provides you with energy. So that means we're a source! No, wait a minute, where did those sugars come from? You ate them! This is exactly why we eat, to ingest the nutrients that will supply us with energy. So think about that for a second: we eat foods that have carbon in various organic molecules, which we break down to get energy, and CO2 is made as a byproduct and respired.

But that means humans (and all animals) make CO2 and put it into the air.

Yeah, but it all comes from somewhere. Let's take me as a simple example, or a cow. The point being, the cow and I are vegetarians, so most of the CO2 we respire comes from breaking down plant matter. Where does the carbon in that plant matter come from? Remember what we all learned as kids, plants breathe in CO2 and breathe out oxygen. Yes, plants take the CO2 right out of the air. They take CO2 from the air, water from the soil, and sunlight, and perform photosynthesis, which is to say 6CO2 + 6H2O → C6H12O6 + 6O2. Like magic, isn't it. On the right side are just 6 molecules of oxygen along with a sugar molecule that is holding onto some carbon and oxygen, which I'll eat and break down for energy, releasing CO2. Magic.

So there's a balance... like a cycle of carbon in the biosphere. This is why, in principle, biofuels should be carbon neutral. Breaking down plant matter moves CO2 around, eventually expelling it into the atmosphere, but eventually it is sucked back into the biosphere by autotrophs like plants and phytoplankton.

So what's the problem with burning fossil fuels? Well, that takes carbon from the lithosphere and suddenly introduces it to the atmosphere-biosphere-ocean system. There is normally exchange between the lithosphere and the rest of the climate system, but that is a very slow process, which combustion accelerates. There's no where for that extra CO2 to go because each part of the cycle only has so much wiggle room. The result is a build-up of CO2 in the atmosphere, where it enhances the greenhouse effect, and chaos ensues. Carbon dioxide isn't a pollutant like CFCs, then, but the carbon dioxide emitted by burning fossil fuels is basically the same. Whatever oil, coal, or natural gas is pulled out of the rocks needs to be accounted for, because that is the potentially harmful carbon.

2009-04-28

“There isn’t even one study that can be produced that shows that carbon dioxide is a harmful gas” says Rep. Michele Bachmann

One of my least favorite members of Congress these days is the representative from Minnesota, Michele Bachmann. This might not be totally true, as she is a wealth, a cornucopia, of craziness that I normally only get to enjoy late at night listening to Coast-to-Coast-AM. She is a member of Congress, but seems to have little grasp of reality, and certainly no grasp of science. Below is a video clip of her on the floor of the House (via Kate Sheppard... via Wonk Room).


Wow.

Let's not get into the details. Let's just all agree that, yes, carbon dioxide is a naturally occurring gas, and that it is a trace gas in the atmosphere. But let's also agree that carbon dioxide can be a deadly poison!

2009-04-21

China gently asked to please think about playing nice someday

The International Energy Agency (IEA) has approached China, "warning" the country that it needs to reduce carbon emissions. [LINK] Will China take this warning to heart, and start cleaning up its act? Well, considering that 80% of China's electricity is from burning coal, and the well-used statistics that China is opening a new coal-fired power plant every week, I think not. 

Maybe I'm just feeling pessimistic today, but I just don't see China and India shaping  up in time to stop atmospheric CO2 levels reaching 450, and probably 550, ppm. The two countries have more than 2 billion people, and are both "developing" nations, which now seems to mean nations that are trying to replicate what the USA and other "Western" nations did 50 years ago. The desire to "catch up" with the developed world is so great that these giants can not rationally address climate issues. 

What is the solution? Well, ignoring geoengineering for now, the only way to get China and India to shift away from fossil fuels is to demonstrate a better system, that is more efficient and at least as cheap as the fossil fuel based one that has taken hold. One big obstacle on that front is that China has enormous coal reserves, so burning coal is amazingly cheap in China, and it's hard to imagine an energy system that will be cheaper for China than coal. That even holds for a system that will be cheap in, say, the USA, since such a system would either be sold to China or reverse-engineered, which would incur additional costs.

The IEA warns of some kind of regulation, which I guess could be effective if such regulations were very widely adopted. That would add up to the same kind of carbon tariffs that India wants to avoid. The problem is that China is such a gigantic manufacturer that it would be difficult for many countries (e.g., the USA) to penalize China without hurting themselves. Clearly this is a sticky issue, and there's not a good solution. The problem is that a solution is desperately needed to avoid dangerous levels of anthropogenic climate change.

UPDATE:
I just came across an article in New Scientist that suggests China and the USA might be coming together on plans for reduced carbon emissions. In actuality, these are two unrelated stories. The one about China is kind of interesting. China's climate negotiator, Su Wei, says that in their next 5-year plan, China will likely reduce the "carbon intensity" of their energy production. Here's what he says, "China hasn't reached the stage where we can reduce overall emissions, but we can reduce energy intensity and carbon intensity." What does that mean? Not much. As I have to keep saying, it doesn't matter what the carbon emissions per capita are, only the total amount of carbon. Just because China will become more efficient in their use of energy doesn't mitigate global warming. In fact, by continuing to increase carbon emission, China continues to exacerbate the problem.

2009-04-13

India won't play nice

An article by Rama Lakshmi in the Washington Post is a reminder that despite the increasing concern about global warming and carbon emissions, developing nations still want to develop without constraint. Put pretty succinctly by one of the Indian delegates to a recent UN conference, "It is morally wrong for us to agree to reduce [carbon emissions] when 40 percent of Indians do not have access to electricity."

The article goes on to say, "Last week, India's special envoy on climate change, Shyam Saran, told reporters in Bonn that he opposed any attempt by the European Union and the United States to impose 'carbon tariffs' on exports of Indian goods produced in energy-intensive industries such as steel, aluminum, cement and fertilizer." It also says that India doesn't think it is fair to be targeted for its emissions because per capita India emits 1/10 of what the US does.

The problem, clearly, is that the population of India is over 1 billion people, and growing. A second problem is that the climate system just doesn't care about the population; the temperature rises in direct proportion to the amount of carbon dioxide in the atmosphere, without dividing by the number of humans who put it there.

There are tricky ethical issues here, and there is no absolutely right answer. India does deserve to continue to develop, bringing the standard of living up for its citizens. India must take responsibility for its contribution to global warming, which threatens the standard of living for just as many people around the world (through changes in precipitation, sea-level, ecosystem response, melting of permafrost, changing migratory patterns, etc).

What can the UN or the United States do to spur India to action, to make a real effort to reduce CO2 emissions? Well, not a whole lot for now. However, going back to Shyam Saran's comment above, I see no reason not to impose carbon tariffs in the near future. This will depend on the adoption of some kind of carbon pricing mechanism (e.g., "cap and trade"). Once a price is placed on carbon use, then it will have to be applied to imports as well, including the amount of energy that goes into transporting material goods.

From my simple viewpoint, which might be naive, it seems like there would absolutely have to be such tariffs. Otherwise, it would become even cheaper to outsource jobs to developing countries. This includes non-manufacturing. Already it is very cheap for companies in the US (and elsewhere) to hire Indian companies to do a lot of work (see e.g., The World is Flat
). If energy costs were to rise substantially in the US because of the price of carbon emissions, without a commensurate rise in price of outsourcing, then there would be little choice left other than to send those jobs overseas, which would be a severe blow to the local economy. So a carbon pricing system imposed, say, on American companies would necessarily include the carbon emitted by their contractors, provided that the contractors are not already paying for those emissions. The job of tracking all the emissions and who pays for what seems gargantuan and nearly intractable. In the end, the whole goal of the system would be to get enough people paying enough money that large-scale shifts in energy generation would ensue, eventually eliminating the need for burning fossil fuels. But the path is tortuous, even if paved with good intentions.


2009-02-24

OCO crashes and burns

Well, about 6 hours ago (as of writing time), a Taurus XL rocket built by Orbital Sciences Corporation of Virginia ignited and launched from Vandenberg Air Force Base. It was carrying the Orbiting Carbon Observatory on board, which was a new NASA satellite designed to very accurately (and sensitively) detect carbon dioxide. The goal was to better describe the sources and sinks of atmospheric carbon dioxide. However, that mission will now fall more heavily on the similar Japanese satellite called Ibuki than planned because a few minutes after launching, the Taurus XL's second stage didn't fully complete, leaving a part of the rocket attached to the 3rd and 4th stages, weight that could not be accommodated. The rocket crashed into the Southern Ocean, currently a large sink for atmospheric carbon dioxide A few more details at NYTimes.com [LINK]

2007-04-30

ye olde iron fertilizing effect

So apparently people now think they can make money by throwing iron into the ocean... YES, throwing iron into the ocean.

Here's the, actually very good, story on NYTimes.com: [The Energy Challenge: Recruiting Plankton to Fight Global Warming]

The basic idea is that plankton reproduce like mad when the conditions are right, and in large swaths of the ocean the conditions are right. Except there isn't enough iron. So, when you dump some iron on those areas, plankton bloom, creating regions of increased biological activity. The upside to this, according to some, is that the plankton use carbon from the ocean to make their little calcium carbonate exoskeletons, which when the critters die, can sink to the bottom of the ocean. This means that carbon is removed from the atmosphere-ocean system... it is sequestered, like an OJ juror. So now at least two companies, so cleverly named Planktos and Climos, think they can get governments (or companies working under cap and trade systems) to pay them to go throw some iron into the ocean.

I do not reject this idea outright. There are clearly some good ideas here, but we have to be careful. Here are a couple of my primary concerns.

First, I'm worried that these plankton species will produce a lot of methane waste, possibly negating any decrease in atmospheric CO2 that they might be responsible for. There is similar concern with nitrous oxide, apparently.

Second, the amount of carbon actually deposited might be less than has been thought recently. This is actually in this week's Science [LINK].

Third, as these operations scale up, will they account for their own carbon emissions. Boats are notoriously bad for emissions, and there's going to have to be a lot of boating involved. Also, where is this iron coming from, and how much energy (i.e., carbon) is going into collecting and transporting it?

Finally, there are possible feedbacks that could negate any good this will do. Including the old DMS-cloud condensation nuclei, in which more biology produces more aerosol (in the form of dimethylsulfide, DMS) which acts as nucleation sites for cloud droplets, making more cloud. The effect could be to shade the surface, reduce SST, and thus reduce biological productivity, leaving a rusty sea surface instead of a nice, healthy green one. I don't know if this is feasible, but things like this always seem to come up.

Also consider the amount of carbon dioxide that needs to be removed from the atmosphere. I've just come from a talk that reminded me of this. Carbon dioxide, when frozen, has about the same density as water. That means that a ton of CO2 is about one cubic meter (size of a coffee table). You're now talking about removing billions of tons of carbon dioxide annually, which is an enormous mass, many cubic kilometers of frozen CO2. The ocean is a big place, but we've got to be careful about how and where such deposits are made, or they'd just be mixed back up to the atmosphere. There's just so many potential pitfalls that it is hard to imagine a successful implementation. But as I said at the beginning, I'm willing to keep an open mind on the subject, and would be happy to see a successful strategy.